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Hedinger, R ; Ghisletta, M ; Hegetschweiler, K ; Toth, E ; Merbach, AE ; Sessoli, R ; Gatteschi, D ; Gramlich, V

Trinuclear lanthanoid complexes of 1,3,5-triamino-1,3,5-trideoxy-cis-inositol with a unique, sandwich-type cage structure

Inorganic Chemistry 37 (26) 6698-6705

par Administrateur - publié le

Abstract :

A variety of trinuclear complexes [M-3(H-3L)(2)](3+) [M = Y, La, Eu, Gd, Dy ; L = 1,3,5-triamino-1,3,5-trideoxy cis-inositol (taci) and 1,3,5-trideoxy-1,3,5-tris(dimethylamino) (tdci)] was prepared as solid materials of the composition M-3(H-3L)(2)X-3. pH(2)O . qEtOH (X = Cl, NO3 ; 2.5 less than or equal to p less than or equal to 9 ; q = 0, 0.33) and characterized by elemental analyses, NMR spectroscopy, and FAB(+) mass spectrometry.